Ceph RBD can technically support multi-writer access through exclusive locking, but it won't be the same as multi-writer.
You can set up a radosgw outside of the proxmox and use objects.
But ceph is fundamentally a distributed object store, shared LUNs with block level multi-writer is fundamentally a tightly coupled solution.
If you have a legacy need that has OCFS or a quorum drive, the underlying tools proxmox is an abstraction can sometimes be used as these types of systems tend to be pets.
But if you were just using multi-writer because it was there, there are alternatives that are typically more robust under the shared nothing model like Ceph uses.
From what I read about VMFS yes ceph allows you to have a shared block devices (RBD = rados block devices) across a cluster, and proxmox VE HA makes sure only one instance of the VM is active on the cluster to avoid having multiple writers to the same disk image.
Can it be used to format a single shared block device that is accessed by multiple hosts like VMFS does? My understanding is this isn't possible.